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SHAPE SELECTIVE REACTIONS OF SOME ORGANIC-COMPOUNDS ON THE ZEOLITE KZ-1

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Title SHAPE SELECTIVE REACTIONS OF SOME ORGANIC-COMPOUNDS ON THE ZEOLITE KZ-1
 
Creator RANE, SJ
CHAKRABARTY, DK
 
Subject toluene disproportionation
xylene isomerization
zsm-5 zeolites
meta-xylene
catalysts
alkylation
ethylbenzene
deposition
methanol
ethylbenzene alkylation
ethylbenzene decomposition
kz-1
magic angle spinning nmr of kz-1
shape selectivity
toluene alkylation
zeolites
 
Description Reaction of ethylbenzene, alkylation of toluene with methanol and that of ethylbenzene with ethanol have been studied on the medium pore, high silica zeolite KZ-1 under varying experimental conditions. The zeolite showed a stable catalytic activity and verv high selectivity for the formation of para-dialkylbenzenes. The results suggest that the zeolite KZ-1 has a unidimensional channel structure with ten-membered ring opening, possibly with elliptical shape.
 
Publisher ELSEVIER SCIENCE BV
 
Date 2011-07-26T16:34:37Z
2011-12-26T12:55:12Z
2011-12-27T05:43:53Z
2011-07-26T16:34:37Z
2011-12-26T12:55:12Z
2011-12-27T05:43:53Z
1993
 
Type Article
 
Identifier APPLIED CATALYSIS A-GENERAL, 93(2), 191-202
0926-860X
http://dx.doi.org/10.1016/0926-860X(93)85193-S
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6963
http://hdl.handle.net/10054/6963
 
Language en