Record Details

Mono- and di-nuclear Cu(II) complexes of p-tert-butyl-calix[4]arene-1,3-diacid derivative: A comparative study of their characterization and catecholase mimetic activity

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Mono- and di-nuclear Cu(II) complexes of p-tert-butyl-calix[4]arene-1,3-diacid derivative: A comparative study of their characterization and catecholase mimetic activity
 
Creator ALI, A
SALUNKE-GAWALI, S
RAO, CP
LINARES, J
 
Subject copper(ii) complexes
crystal-structure
lower rim
pendants
oxidases
 
Description Reaction of copper(II) perchlorate with p-tert-butyl-calix[4]arene-1,3-diacid gives mono-nuclear complex in acetonitrile and dinuclear complex in methanol which have been isolated as their pyridine bound adducts. The dinuclear complex exhibits different characteristics in its EPR and magnetic studies. The reactivity studies clearly indicate that the dinuclear complex has higher catecholase mimetic activity over its mononuclear counterpart owing to its coordination favourability.
 
Publisher NATL INST SCIENCE COMMUNICATION
 
Date 2011-08-19T05:48:53Z
2011-12-26T12:56:05Z
2011-12-27T05:44:14Z
2011-08-19T05:48:53Z
2011-12-26T12:56:05Z
2011-12-27T05:44:14Z
2006
 
Type Article
 
Identifier INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 45(4), 853-857
0376-4710
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10245
http://hdl.handle.net/10054/10245
 
Language en