Substituent directed distal photoisomerisation of > C=C < in indolic dienyl chromophores
DSpace at IIT Bombay
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Title |
Substituent directed distal photoisomerisation of > C=C < in indolic dienyl chromophores
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Creator |
SINGH, AK
HOTA, PK |
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Subject |
cis-trans isomerization
photochemistry photophysics vision rhodopsin polyenes model indolic ethenes indolic ethenoates photoisomerisation substituent effect solvent effect |
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Description |
Methyl-3-methyl-5-(3-N-benzenesulphonylindole)-2E,4E-pentadienoate and methyl-3-methyl-5-(3-N-H indole)-2E,4E-pentadienoate are synthesized and their photoisomerisation behaviour in 1.4-dioxane and methanol are examined. The photoisomerisation of these compounds is highly dependent upon the substituent present at the indolic nitrogen atom.
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Publisher |
NATL INST SCIENCE COMMUNICATION
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Date |
2011-08-19T07:01:56Z
2011-12-26T12:56:07Z 2011-12-27T05:44:18Z 2011-08-19T07:01:56Z 2011-12-26T12:56:07Z 2011-12-27T05:44:18Z 2006 |
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Type |
Article
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Identifier |
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 45(11), 2469-2473
0376-4699 http://dspace.library.iitb.ac.in/xmlui/handle/10054/10265 http://hdl.handle.net/10054/10265 |
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Language |
en
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