Thermal rearrangement of the Diels-Alder dimer of 2,6-dimethyl-6-hydroxycyciohexa-2,4-dienone to a pentacyclic dimer
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Title |
Thermal rearrangement of the Diels-Alder dimer of 2,6-dimethyl-6-hydroxycyciohexa-2,4-dienone to a pentacyclic dimer
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Creator |
BATES, RB
CALDERA, S DEOTA, PT KANE, VV SINGH, VK |
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Description |
In the absence of a reactive alkene, the Diels-Alder dimer of 2,6-dimethyl-6-hydroxycyclohexa-2,4-dienone rearranges at 160 degrees C to a new dimer via a reverse Diels-Alder reaction, two alpha-hydroxyketone rearrangements, two Michael additions, and two aldol condensations. (C) 1997 .
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Publisher |
PERGAMON-ELSEVIER SCIENCE LTD
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Date |
2011-08-27T01:18:20Z
2011-12-26T12:57:39Z 2011-12-27T05:44:32Z 2011-08-27T01:18:20Z 2011-12-26T12:57:39Z 2011-12-27T05:44:32Z 1997 |
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Type |
Article
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Identifier |
TETRAHEDRON LETTERS, 38(14), 2405-2408
0040-4039 http://dx.doi.org/10.1016/S0040-4039(97)00368-7 http://dspace.library.iitb.ac.in/xmlui/handle/10054/11491 http://hdl.handle.net/10054/11491 |
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Language |
en
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