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Thermal rearrangement of the Diels-Alder dimer of 2,6-dimethyl-6-hydroxycyciohexa-2,4-dienone to a pentacyclic dimer

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Title Thermal rearrangement of the Diels-Alder dimer of 2,6-dimethyl-6-hydroxycyciohexa-2,4-dienone to a pentacyclic dimer
 
Creator BATES, RB
CALDERA, S
DEOTA, PT
KANE, VV
SINGH, VK
 
Description In the absence of a reactive alkene, the Diels-Alder dimer of 2,6-dimethyl-6-hydroxycyclohexa-2,4-dienone rearranges at 160 degrees C to a new dimer via a reverse Diels-Alder reaction, two alpha-hydroxyketone rearrangements, two Michael additions, and two aldol condensations. (C) 1997 .
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-27T01:18:20Z
2011-12-26T12:57:39Z
2011-12-27T05:44:32Z
2011-08-27T01:18:20Z
2011-12-26T12:57:39Z
2011-12-27T05:44:32Z
1997
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 38(14), 2405-2408
0040-4039
http://dx.doi.org/10.1016/S0040-4039(97)00368-7
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11491
http://hdl.handle.net/10054/11491
 
Language en