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TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS, SPECTROSCOPY, ELECTROCHEMISTRY AND MAGNETIC STUDIES OF CHROMIUM(III)-HEXOSE COMPLEXES AND THEIR IN-VITRO INTERACTION WITH DNA

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Title TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS, SPECTROSCOPY, ELECTROCHEMISTRY AND MAGNETIC STUDIES OF CHROMIUM(III)-HEXOSE COMPLEXES AND THEIR IN-VITRO INTERACTION WITH DNA
 
Creator RAO, CP
KAIWAR, SP
RAGHAVAN, MSS
 
Subject amino-acid
d-glucose
chromium(vi)
reduction
chromate
ions
derivatives
cations
binding
cells
 
Description Saccharide complexes of Cr(III) were synthesized via chromate reduction. Hexose monosaccharides such as D-glucose, D-fructose, D-galactoSe, D-mannose and L-sorbose and some acid derivatives, such as D-galacturonic acid and D-gluconic acid, were used. The final Cr(III) products were isolated, purified and characterized by various analytical, spectroscopic, magnetic and electrochemical methods. All the products reported here are shown to be dinuclear in nature. The inherent stability and robust nature of these complexes is demonstrated and they are shown to affect the pSV2neo plasmid (DNA) structure in gel electrophoretic experiments.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-27T02:01:54Z
2011-12-26T12:57:40Z
2011-12-27T05:44:41Z
2011-08-27T02:01:54Z
2011-12-26T12:57:40Z
2011-12-27T05:44:41Z
1994
 
Type Article
 
Identifier POLYHEDRON, 13(12), 1895-1906
0277-5387
http://dx.doi.org/10.1016/0277-5387(94)80013-8
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11503
http://hdl.handle.net/10054/11503
 
Language en