Record Details

1,3-dipolar cycloaddition reaction of alpha,beta-unsaturated esters and lactones with diazomethane.

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title 1,3-dipolar cycloaddition reaction of alpha,beta-unsaturated esters and lactones with diazomethane.
 
Creator BASKARAN, S
VASU, J
PRASAD, R
KODUKULLA, K
TRIVEDI, GK
CHANDRASEKHAR, J
 
Subject cyclo-addition
diazoalkanes
 
Description 1,3-Dipolar cycloaddition of diazomethane to the alpha,beta-unsaturated esters and lactones such as 2-4, 6-8, 10 and 13 occurs in a stereoselective manner affording conjugated Delta(2)-pyrazolines. E and Z isomers of D-mannitol lead to identical product which was cyclised to investigate the absolute stereochemistry of the product. The regiospecificities of all the reactions are consistent with FMO coefficients obtained through AM1 calculations.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-22T08:38:32Z
2011-12-26T12:56:16Z
2011-12-27T05:44:43Z
2011-08-22T08:38:32Z
2011-12-26T12:56:16Z
2011-12-27T05:44:43Z
1996
 
Type Article
 
Identifier TETRAHEDRON, 52(12), 4515-4526
0040-4020
http://dx.doi.org/10.1016/0040-4020(96)00099-3
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10376
http://hdl.handle.net/10054/10376
 
Language en