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A NOVEL PERISELECTIVE CYCLOADDITION OF CYCLOHEPTATRIENE WITH CYCLOHEXA-2,4-DIENONES

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Title A NOVEL PERISELECTIVE CYCLOADDITION OF CYCLOHEPTATRIENE WITH CYCLOHEXA-2,4-DIENONES
 
Creator SINGH, V
PORINCHU, M
 
Subject cyclo-additions
regioselectivity
 
Description A highly periselective cycloaddition of cycloheptatriene and cyclohexa-2,4-dienones(2a-c) to endo tricyclic systems (6a-c) and their photo conversion to cage compunds (7a-c ) has been reported. It has been shown that the adduct 6c arise via Cope rearrangement of the initially formed pi4s(dienone) + pi2s(CHT) adduct 5c.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-23T08:13:28Z
2011-12-26T12:56:22Z
2011-12-27T05:45:03Z
2011-08-23T08:13:28Z
2011-12-26T12:56:22Z
2011-12-27T05:45:03Z
1993
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 34(17), 2817-2820
0040-4039
http://dx.doi.org/10.1016/S0040-4039(00)73570-2
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10452
http://hdl.handle.net/10054/10452
 
Language en