Record Details

Contrasting behavior of bis[2-(4,4-dimethyl-2-oxazolinyl)phenyl] chalcogenides (Se/Te) toward mercuric chloride: Facile cleavage of the Te-C bond

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Contrasting behavior of bis[2-(4,4-dimethyl-2-oxazolinyl)phenyl] chalcogenides (Se/Te) toward mercuric chloride: Facile cleavage of the Te-C bond
 
Creator APTE, SD
ZADE, SS
SINGH, HB
BUTCHER, RJ
 
Subject macrocyclic schiff-base
molecular-structure
asymmetric methoxyselenenylation
organic tellurides
crystal-structures
complexes
chemistry
halides
bromide
diselenides
 
Description The reactions of R2Se (3) and R2Te (4) (R = 2-(4,4-dimethyl-2-oxazolinyl)phenyl) with HgCl2 and Pd(COD)Cl-2 are described. The reaction of selenoether 3 with HgCl2 affords the expected complex R2SeHgCl2 (5), which is stable in solution. In contrast, the analogous tellurium complex R2TeHgCl2 (6) undergoes slow dismutation in chlorinated solvents to give the fragments RTeCl (7) and RHgCl (8).
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-13T21:02:07Z
2011-12-26T12:48:08Z
2011-12-27T05:45:12Z
2011-07-13T21:02:07Z
2011-12-26T12:48:08Z
2011-12-27T05:45:12Z
2003
 
Type Article
 
Identifier ORGANOMETALLICS, 22(26), 5473-5477
0276-7333
http://dx.doi.org/10.1021/om034222s
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3771
http://hdl.handle.net/10054/3771
 
Language en