CONVENIENT SYNTHESIS OF DECALIN SYSTEMS OF BIOACTIVE TERPENOIDS
DSpace at IIT Bombay
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Title |
CONVENIENT SYNTHESIS OF DECALIN SYSTEMS OF BIOACTIVE TERPENOIDS
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Creator |
GORE, VK
DESAI, SR MAYELVAGANAN, T PADMAKUMAR, R HADIMANI, SB BHAT, SV |
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Subject |
diels-alder reactions
forskolin |
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Description |
New analogues of bioactive terpenoids, forskolin, nimbolide, isozonarol and ambrox have been synthesized using general Diels-Alder reaction of 2-formyl-4,4-dimethyl-cyclohexa-2,5-dienone (7) with 1,2-disubstituted-1,3-dienes (8a-k) which yielded endo- & exo-adducts. The deformylation, epimerisation, angular methylation, reduction and oxidation studies on these adducts have been reported.
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Publisher |
PERGAMON-ELSEVIER SCIENCE LTD
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Date |
2011-08-23T20:49:50Z
2011-12-26T12:56:35Z 2011-12-27T05:45:34Z 2011-08-23T20:49:50Z 2011-12-26T12:56:35Z 2011-12-27T05:45:34Z 1993 |
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Type |
Article
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Identifier |
TETRAHEDRON, 49(13), 2767-2782
0040-4020 http://dx.doi.org/10.1016/S0040-4020(01)86353-5 http://dspace.library.iitb.ac.in/xmlui/handle/10054/10639 http://hdl.handle.net/10054/10639 |
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Language |
en
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