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TRANSITION-METAL SACCHARIDE CHEMISTRY - D-GLUCOSE COMPLEXES OF MN(II), CO(II), NI(II), CU(II) AND ZN(II)

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Title TRANSITION-METAL SACCHARIDE CHEMISTRY - D-GLUCOSE COMPLEXES OF MN(II), CO(II), NI(II), CU(II) AND ZN(II)
 
Creator BANDWAR, RP
RAGHAVAN, MSS
RAO, CP
 
Subject potassium chromate
d-fructose
ions
cations
coordination
reduction
co(ii)
complexes
cu(ii)
glucose
mn(ii)
ni(ii)
saccharide
transition metal
zn(ii)
 
Description Metal complexes of D-glucose (D-Glc) from large cation containing dibromo-dichloro salts of dipositive metals [NEt(4)](2)[MBr(2)Cl(2)] (M = Mn, Co, Ni, Cu and Zn) and the disodium salt of glucose were synthesized from a MeOH:MeCN mixture. The complexes were characterized by UV-vis absorption, circular dichroism, IR and proton magnetic resonance spectroscopies, and by elemental analysis, and were found to be Na[M(D-Glc)(OMe)Cl]. Cyclic voltammetric studies of these complexes, in the acidic to neutral pH range, indicated no dissociation, even in highly acidic conditions.
 
Publisher RAPID SCIENCE PUBLISHERS
 
Date 2011-08-27T10:12:14Z
2011-12-26T12:57:52Z
2011-12-27T05:45:43Z
2011-08-27T10:12:14Z
2011-12-26T12:57:52Z
2011-12-27T05:45:43Z
1995
 
Type Article
 
Identifier BIOMETALS, 8(1), 19-24
0966-0844
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11628
http://hdl.handle.net/10054/11628
 
Language en