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Enantiospecific synthesis of [7R,6S,5S,4R]-triacetoxy-(-)-goniotriol

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Title Enantiospecific synthesis of [7R,6S,5S,4R]-triacetoxy-(-)-goniotriol
 
Creator SRIKANTH, GSC
KRISHNA, UM
TRIVEDI, GK
 
Subject goniothalamus-giganteus annonaceae
styryl-lactones
(+)-goniofufurone
(+)-goniotriol
goniofufurone
styryllactones
goniotriol
ring closing metathesis
pcc oxidation
 
Description A short and efficient synthesis of [7R,6S,5S,4R]-triacetoxy-(-)-goniotriol starting form D-glucose is described. A sequence of ring closing metathesis (RCM) followed by a PCC oxidation was used to construct the core six-membered alpha,beta-unsaturated lactone moiety. (C) 2002 . .
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-24T06:31:35Z
2011-12-26T12:56:46Z
2011-12-27T05:45:59Z
2011-08-24T06:31:35Z
2011-12-26T12:56:46Z
2011-12-27T05:45:59Z
2002
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 43(31), 5471-5473
0040-4039
http://dx.doi.org/10.1016/S0040-4039(02)01048-1
http://dspace.library.iitb.ac.in/xmlui/handle/10054/10789
http://hdl.handle.net/10054/10789
 
Language en