Conductivity and dielectric studies on LiCeO(2)
DSpace at IIT Bombay
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Title |
Conductivity and dielectric studies on LiCeO(2)
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Creator |
PRABU, M
SELVASEKARAPANDIAN, S KULKARNI, AR HIRANKUMAR, G SANJEEVIRAJA, C |
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Subject |
li-ion battery
spinel limn2o4 lithium insertion cathode lithium-ion batteries impedance conductivity dielectric analysis complex modulus rare earths |
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Description |
LiCeO(2) was prepared by a solid-state reaction method using microwave heat treatment and identified by X-ray diffractometry. LiCeO(2) has monoclinic crystal structure whose conductivity and dielectric properties were studied over a range of frequency (42 Hz to 1 MHz) and temperatures (30-500 degrees C) using ac technique of complex impedance analyzer HIOKI 3532. Combined impedance and modulus plots were used as tools to analyze the sample behaviour as a function of frequency at different temperatures. The d.c. conductivity (sigma(dc)) followed the Arrhenius relation. The modulus analysis and dielectrics studies showed the non-Debye dielectric relaxation nature.
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Publisher |
ELSEVIER SCIENCE BV
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Date |
2011-07-24T14:35:17Z
2011-12-26T12:57:58Z 2011-12-27T05:46:33Z 2011-07-24T14:35:17Z 2011-12-26T12:57:58Z 2011-12-27T05:46:33Z 2010 |
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Type |
Article
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Identifier |
JOURNAL OF RARE EARTHS, 28(3), 435-438
1002-0721 http://dx.doi.org/10.1016/S1002-0721(09)601211-9 http://dspace.library.iitb.ac.in/xmlui/handle/10054/6452 http://hdl.handle.net/10054/6452 |
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Language |
en
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