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Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocycles towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage

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Title Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocycles towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C-Pt-Se linkage
 
Creator PANDA, S
SINGHA, HB
BUTCHER, RJ
 
Subject x-ray-structure
crystal-structure
schiff-base
complexes
tellurium
chemistry
platinum(ii)
selenoether
ligands
palladium(ii)
 
Description Interaction of the 22-membered selenaaza macrocyle 3 with Pt(II) leads to the formation of the novel cationic Pt(IV) metallamacrocylic complex 5 via the oxidative addition of a C-Se bond to Pt(II), whereas corresponding reactions of 3 and 4 with Pd(II) afford cationic complexes 6 and 7 with differing ligating properties.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T09:09:35Z
2011-12-26T12:57:58Z
2011-12-27T05:46:38Z
2011-08-28T09:09:35Z
2011-12-26T12:57:58Z
2011-12-27T05:46:38Z
2004
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, (3), 322-323
1359-7345
http://dx.doi.org/10.1039/b312358h
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11700
http://hdl.handle.net/10054/11700
 
Language en