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Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2 pi partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones

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Title Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2 pi partners: a novel and stereoselective route to functionalised bicyclo[2.2.2]octenones
 
Creator SINGH, V
PAL, S
MOBIN, SM
 
Subject masked o-benzoquinones
diels-alder reactions
ring-systems
rearrangement
derivatives
 
Description A novel route to functionalised bicyclo[2.2.2]octenones via pi(4s) + pi(2s) cycloaddition of cyclohexa-2,4-dienones with electron deficient 2 partners, and crystal structure of 1,7-dimethyl-5-hydroxy-5-chloromethyl-2-carboethoxy bicyclo[ 2.2.2] oct-7-ene-6-one, is reported.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T09:34:52Z
2011-12-26T12:57:59Z
2011-12-27T05:46:41Z
2011-08-28T09:34:52Z
2011-12-26T12:57:59Z
2011-12-27T05:46:41Z
2002
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, (18), 2050-2051
1359-7345
http://dx.doi.org/10.1039/b205475m
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11705
http://hdl.handle.net/10054/11705
 
Language en