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EPR AND PROTON ENDOR STUDIES IN SINGLE-CRYSTALS OF POTASSIUM HYDROGEN THIODIACETATE

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Title EPR AND PROTON ENDOR STUDIES IN SINGLE-CRYSTALS OF POTASSIUM HYDROGEN THIODIACETATE
 
Creator KUMAR, MR
LINGAM, KV
RAO, TKG
 
Description Radicals trapped in a gamma-irradiated single crystal of potassium hydrogen thiodiacetate have been investigated using the techniques of EPR and ENDOR. A radical of the type HO2C-CH2-S-CH-CO2H was observed and analysed. The second radical could not be analysed, owing to overlap of the spectrum and only information about the g factors could be obtained. The third radical observed was of the type RCH2-S, formed by the scission of the S-C bond, and was observable only at low temperatures (below -100-degrees-C), and was characterized by highly anisotropic g factors.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T10:46:31Z
2011-12-26T12:58:00Z
2011-12-27T05:46:48Z
2011-08-28T10:46:31Z
2011-12-26T12:58:00Z
2011-12-27T05:46:48Z
1991
 
Type Article
 
Identifier JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 87(2), 273-277
0956-5000
http://dx.doi.org/10.1039/ft9918700273
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11719
http://hdl.handle.net/10054/11719
 
Language en