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Molecular complexity from aromatics: Synthesis and photoreaction of endo-tricyclo[5.2.2.0(2,6)]undecane - A stereoselective route to tricyclic framework of protoilludanes

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Title Molecular complexity from aromatics: Synthesis and photoreaction of endo-tricyclo[5.2.2.0(2,6)]undecane - A stereoselective route to tricyclic framework of protoilludanes
 
Creator SINGH, V
LAHIRI, S
PAL, S
 
Subject natural sesquiterpenoids
laurilia-tsugicola
metabolites
illudol
cycloaddition
photochemical 1,3-acyl shift
 
Description A stereoselective route towards protoilludanoids from simple aromatic precursor is described. The methodology involves in situ generation of spiroepoxycyclohexadienone and cycloaddition with cyclopentadiene and photochemical 1,3-acyl shift. (c) 2005
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-25T14:38:39Z
2011-12-26T12:57:07Z
2011-12-27T05:46:55Z
2011-08-25T14:38:39Z
2011-12-26T12:57:07Z
2011-12-27T05:46:55Z
2005
 
Type Article
 
Identifier BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 15(19), 4367-4369
0960-894X
http://dx.doi.org/10.1016/j.bmcl.2005.06.030
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11051
http://hdl.handle.net/10054/11051
 
Language en