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Molecular complexity from aromatics: synthesis of highly functionalized spiro delta-lactones

DSpace at IIT Bombay

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Title Molecular complexity from aromatics: synthesis of highly functionalized spiro delta-lactones
 
Creator SINGH, V
SINGH, V
 
Subject gamma-lactones
derivatives
metathesis
construction
routes
spirolactones
furyl alcohols
oxidative dearomatization
ring-closing metathesis
medium-sized rings
 
Description A novel, general, and efficient method has been developed for the synthesis of highly functionalized spiro delta-lactones from aromatic precursors. Our methodology involves a tandem oxidative dearomatization-rearrangement of tertiary furyl carbinols and ring-closing metathesis as key features. This method allows an access to the spirolactones attached to carbocycles of various sizes. (C) 2009
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-25T14:45:41Z
2011-12-26T12:57:07Z
2011-12-27T05:46:55Z
2011-08-25T14:45:41Z
2011-12-26T12:57:07Z
2011-12-27T05:46:55Z
2009
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 50(25), 3092-3094
0040-4039
http://dx.doi.org/10.1016/j.tetlet.2009.04.019
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11053
http://hdl.handle.net/10054/11053
 
Language en