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Novel synthesis of trioxatetracyclo[5.3.2.0.(4,9).0(4,11)]dodecane and bibenzyl skeletons
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Novel synthesis of trioxatetracyclo[5.3.2.0.(4,9).0(4,11)]dodecane and bibenzyl skeletons
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| Creator |
REDDY, PV
MANISEKARAN, T BHAT, SV |
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| Subject |
chemistry
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| Description |
A novel 7,9,11-trimethyl-8,10,12-trioxatetracyclo[5.3.2.0.(4,9).0(4,11)]-dodec-1-yl]-2-butanone skeleton 3 has been synthesized by the treatment of 2-acetyl-3,4-dihydro-2,5-di (3 "-oxo-butyl)-6-methyl-(2H)-pyran 2, with H-ZSM-5. However, the treatment of compound 2 with p-TsOH gives bibenzyls. Present report provides a unique acid catalysed cyclization of diketo-olefin system over zeolite, X-ray crystal structure of 3 is also presented. (C) 1998 . .
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| Publisher |
PERGAMON-ELSEVIER SCIENCE LTD
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| Date |
2011-08-25T17:27:16Z
2011-12-26T12:57:09Z 2011-12-27T05:46:59Z 2011-08-25T17:27:16Z 2011-12-26T12:57:09Z 2011-12-27T05:46:59Z 1998 |
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| Type |
Article
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| Identifier |
TETRAHEDRON LETTERS, 39(12), 1629-1632
0040-4039 http://dspace.library.iitb.ac.in/xmlui/handle/10054/11089 http://hdl.handle.net/10054/11089 |
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| Language |
en
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