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OXOVANADIUM(V) SCHIFF-BASE COMPLEXES OF TRISHYDROXYMETHYLAMINOMETHANE WITH SALICYLALDEHYDE AND ITS DERIVATIVES - SYNTHESIS, CHARACTERIZATION AND REDOX REACTIVITY

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Title OXOVANADIUM(V) SCHIFF-BASE COMPLEXES OF TRISHYDROXYMETHYLAMINOMETHANE WITH SALICYLALDEHYDE AND ITS DERIVATIVES - SYNTHESIS, CHARACTERIZATION AND REDOX REACTIVITY
 
Creator ASGEDOM, G
SREEDHARA, A
RAO, CP
 
Subject ascophyllum-nodosum
vanadium
spectroscopy
chemistry
model
 
Description Five vanadium complexes possessing the VO3+ motif with NO4 coordination have been synthesized and characterized by H-1 and C-13 NMR, UV-Vis, FTIR and cyclic voltammetry. These complexes favour trigonal bipyramidal geometry. In DMF solution, complexes 1 and 5 have shown reversible redox behaviour in the presence of L-ascorbic acid or L-cysteine ethyl ester in air as monitored by electronic absorption and EPR studies.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-25T21:20:29Z
2011-12-26T12:57:13Z
2011-12-27T05:47:12Z
2011-08-25T21:20:29Z
2011-12-26T12:57:13Z
2011-12-27T05:47:12Z
1995
 
Type Article
 
Identifier POLYHEDRON, 14(13-14), 1873-1879
0277-5387
http://dx.doi.org/10.1016/0277-5387(94)00461-M
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11150
http://hdl.handle.net/10054/11150
 
Language en