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pi(4s)+pi(2s) cycloaddition between electron deficient pi-systems and photoreaction of beta,gamma-enones: a novel stereoselective entry into angular triquinanes

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Title pi(4s)+pi(2s) cycloaddition between electron deficient pi-systems and photoreaction of beta,gamma-enones: a novel stereoselective entry into angular triquinanes
 
Creator SINGH, V
LAHIRI, S
 
Subject organic-synthesis
tricyclopentanoids
cyclopropanes
methane
cycloaddition
oxa-di-pi-methane rearrangement
angular triquinane
 
Description Cycloaddition of electron deficient partners such as cyclohexa-2,4-dienone and acrylates leading to an efficient synthesis of complex bicyclo[2.2.2]octenones having a beta,gamma-enone chromophore, and their transformation to angular triquinanes via photoreaction, is described. (C) 2003 . .
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-25T22:53:14Z
2011-12-26T12:57:15Z
2011-12-27T05:47:15Z
2011-08-25T22:53:14Z
2011-12-26T12:57:15Z
2011-12-27T05:47:15Z
2003
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 44(22), 4239-4242
0040-4039
http://dx.doi.org/10.1016/S0040-4039(03)00887-6
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11174
http://hdl.handle.net/10054/11174
 
Language en