Record Details

Organochalcogenido-bridged dimeric 2-methylallylpalladium complexes: synthesis, structure and their transformation into palladium chalcogenides

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Organochalcogenido-bridged dimeric 2-methylallylpalladium complexes: synthesis, structure and their transformation into palladium chalcogenides
 
Creator SINGHAL, A
JAIN, VK
MISHRA, R
VARGHESE, B
 
Subject allylpalladium complexes
chemistry
 
Description Organochalcogenido-bridged dimeric 2-methylallylpalladium complexes of the type [Pd-2(mu-ER)(2)(eta(3)-C4H7)(2)] (1) [ER = SBut (1a), SPh (1b), SC6F5 (1c), SePh (1d), TePh (1e)] have been prepared. The structure of the SBut bridged complex has been established by single crystal X-ray diffraction analysis. The four-membered Pd2S2 ring adopts a non-planar conformation with the two eta(3)-2-MeC3H4 (eta(3)-C4H7) in a syn configuration. The thermal behaviour of these complexes has been investigated by thermogravimetric analysis. These complexes yield Pd4E (E = S or Se) or Pd3Te2 at moderately low temperatures.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T15:28:56Z
2011-12-26T12:58:05Z
2011-12-27T05:47:19Z
2011-08-28T15:28:56Z
2011-12-26T12:58:05Z
2011-12-27T05:47:19Z
2000
 
Type Article
 
Identifier JOURNAL OF MATERIALS CHEMISTRY, 10(5), 1121-1124
0959-9428
http://dx.doi.org/10.1039/a908133j
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11773
http://hdl.handle.net/10054/11773
 
Language en