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ORTHO-VANILLYL ALCOHOL AS A SYNTHETIC EQUIVALENT OF 2-METHOXYCYCLOHEXA-2,4-DIENONES - A NOVEL SYNTHESIS OF LINEARLY FUSED CIS-ANTI-CIS-TRICYCLOPENTANOIDS

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Title ORTHO-VANILLYL ALCOHOL AS A SYNTHETIC EQUIVALENT OF 2-METHOXYCYCLOHEXA-2,4-DIENONES - A NOVEL SYNTHESIS OF LINEARLY FUSED CIS-ANTI-CIS-TRICYCLOPENTANOIDS
 
Creator SINGH, V
THOMAS, B
 
Subject mediated cyclization reaction
(+/-)-hirsutene
photochemistry
oxidation
ketones
phenols
beta
 
Description A novel and efficient synthesis of tricyclopentanoids via inverse demand pi-4s + pi-2s cycloaddition and photochemical reaction of annulated[2.2.2]octenones having an alpha-alkoxy-beta,gamma-unsaturated carbonyl chromophore, is described.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T15:31:45Z
2011-12-26T12:58:05Z
2011-12-27T05:47:20Z
2011-08-28T15:31:45Z
2011-12-26T12:58:05Z
2011-12-27T05:47:20Z
1992
 
Type Article
 
Identifier JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, (17), 1211-1213
0022-4936
http://dx.doi.org/10.1039/c39920001211
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11774
http://hdl.handle.net/10054/11774
 
Language en