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Regioselective total synthesis of (+/-)neorautane, (+/-)neorautanin and their analogs. Microwave mediated synthesis of 2H-chromenes from propargyl phenyl ethers.

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Title Regioselective total synthesis of (+/-)neorautane, (+/-)neorautanin and their analogs. Microwave mediated synthesis of 2H-chromenes from propargyl phenyl ethers.
 
Creator SUBBURAJ, K
KATOCH, R
MURUGESH, MG
TRIVEDI, GK
 
Subject 3+2 cycloaddition reactions
diels-alder reactions
substituted pterocarpans
2-alkoxy-1,4-benzoquinones
1,4-benzoquinones
products
 
Description Herein we describe the total synthesis of (+/-) Neorautane 1. (+/-) Neorautanin 2 and their analogs 15-18. The key intermediates Chromenes 10-13 were synthesised by microwave irradiation of propargyl phenyl ethers 8 and 9 in DMF under pressure. (C) 1997 .
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2011-08-26T06:58:16Z
2011-12-26T12:57:20Z
2011-12-27T05:47:26Z
2011-08-26T06:58:16Z
2011-12-26T12:57:20Z
2011-12-27T05:47:26Z
1997
 
Type Article
 
Identifier TETRAHEDRON, 53(37), 12621-12628
0040-4020
http://dx.doi.org/10.1016/S0040-4020(97)00783-7
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11231
http://hdl.handle.net/10054/11231
 
Language en