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Regioselective total synthesis of edulane and its angular analogue

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Title Regioselective total synthesis of edulane and its angular analogue
 
Creator SUBBURAJ, K
MURUGESH, MG
TRIVEDI, GK
 
Subject 1,4-benzoquinones
pterocarpans
styrenes
 
Description Herein we describe a 10-step total synthesis of edulane 3 and its angular analogue 18 from phloroglucinol. The key step involves ZnCl2-catalysed condensation of the appropriately substituted 2H-chromenes 8, 9 and 10 with the 2-alkoxy-1,4-benzoquinones 11 and 12, respectively.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T16:49:04Z
2011-12-26T12:58:07Z
2011-12-27T05:47:32Z
2011-08-28T16:49:04Z
2011-12-26T12:58:07Z
2011-12-27T05:47:32Z
1997
 
Type Article
 
Identifier JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, (12), 1875-1878
0300-922X
http://dx.doi.org/10.1039/a608227k
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11791
http://hdl.handle.net/10054/11791
 
Language en