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Seeking tetrameric transition metal phosphonate with a D4R core and organising it into a 3-D supramolecular assembly

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Title Seeking tetrameric transition metal phosphonate with a D4R core and organising it into a 3-D supramolecular assembly
 
Creator MURUGAVEL, R
SHANMUGAN, S
 
Subject pyrazole ligands
tetranuclear
aluminophosphonate
transformations
phosphates
elements
cluster
cages
units
 
Description The first cubic zinc phosphonate [tBuPO(3)Zn(2-apy)] 4 (1) whose core resembles the D4R SBU of zeolites, has been synthesised from a reaction between zinc acetate, tert- butylphosphonic acid and 2- aminopyridine at room temperature; the X- ray structure determination reveals that the molecules of 1, which crystallise in the tetragonal I4(1)/a space group with crystallographically imposed 4 symmetry, form a 3-D supramolecular assembly aided by N-(HO)-O-... hydrogen bonding.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T17:59:21Z
2011-12-26T12:58:08Z
2011-12-27T05:47:37Z
2011-08-28T17:59:21Z
2011-12-26T12:58:08Z
2011-12-27T05:47:37Z
2007
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, (12), 1257-1259
1359-7345
http://dx.doi.org/10.1039/b616439k
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11806
http://hdl.handle.net/10054/11806
 
Language en