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Synthesis and single crystal X-ray structure of the first cationic Pd(II) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(II) and Pt(II) with a 22-membered macrocyclic Schiff base

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Title Synthesis and single crystal X-ray structure of the first cationic Pd(II) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(II) and Pt(II) with a 22-membered macrocyclic Schiff base
 
Creator MENON, SC
PANDA, A
SINGH, HB
BUTCHER, RJ
 
Subject selenium coronands
donor atoms
palladium(ii)
reactivity
chemistry
2-(2'-pyridyl)phenyl(para-ethoxyphenyl)tellurium(ii)
behavior
nitrogen
m=pd
 
Description The reaction of the tellurium containing macrocyclic Schiff base 1 with Pd(PhCN)(2)Cl-2 and NH4PF6 gives the expected cationic complex [Pd(II)1][PF6](2); by contrast the reaction of 1 with Pt(cod)Cl-2 proceeds via novel transmetallation to yield an organoplatinum complex.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T20:36:41Z
2011-12-26T12:58:12Z
2011-12-27T05:47:44Z
2011-08-28T20:36:41Z
2011-12-26T12:58:12Z
2011-12-27T05:47:44Z
2000
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS, (2), 143-144
1359-7345
http://dx.doi.org/10.1039/a908683h
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11837
http://hdl.handle.net/10054/11837
 
Language en