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MIXED CHALCOGEN CARBONYL-COMPOUNDS .2. SYNTHESIS AND CHARACTERIZATION OF FE2RU(MU-3-SE)-(MU-3-TE)(CO)9 AND (ETA-5-C5H5)COFE2(MU-3-SE)(MU-3-TE)(CO)6
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
MIXED CHALCOGEN CARBONYL-COMPOUNDS .2. SYNTHESIS AND CHARACTERIZATION OF FE2RU(MU-3-SE)-(MU-3-TE)(CO)9 AND (ETA-5-C5H5)COFE2(MU-3-SE)(MU-3-TE)(CO)6
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| Creator |
CHAKRABARTY, D
HOSSAIN, MM KUMAR, RK MATHUR, P |
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| Subject |
cluster compounds
complexes conversion reactivity chemistry tellurium |
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| Description |
The new mixed metal complexes, each containing bridging selenium and tellurium ligands in the same molecule, Fe2Ru(CO)9(mu-3-Se)(mu-3-Te) and (eta-5-C5H5)CoFe2(CO)6(mu-3-Se)(mu-3-Te) have been prepared from the room temperature reactions of Fe2(CO)6(mu-SeTe) with Ru(CO)4(C2H4) and (C5H5)Co(CO)2, respectively. Reaction of (eta-5-C5H5)CoFe2(CO)6(mu-3-Se)(mu-3-Te) with Pt(PPh3)4 forms the previously known (CO)6Fe2(mu-3-Se)(mu-3-Te)Pt(PPh3)2 and on treatment with NaOMe, followed by acidification, Fe2(CO)6(mu-SeTe) is formed.
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| Publisher |
ELSEVIER SCIENCE SA LAUSANNE
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| Date |
2011-07-29T10:00:22Z
2011-12-26T12:48:37Z 2011-12-27T05:47:51Z 2011-07-29T10:00:22Z 2011-12-26T12:48:37Z 2011-12-27T05:47:51Z 1991 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 410(2), 143-148
0022-328X http://dx.doi.org/10.1016/0022-328X(91)80003-3 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7670 http://hdl.handle.net/10054/7670 |
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| Language |
en
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