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TRANSITION-METAL SACCHARIDE CHEMISTRY AND BIOLOGY - SYNTHESIS, CHARACTERIZATION, REDOX BEHAVIOR, BIOINTERACTION AND DATA CORRELATIONS OF DINUCLEAR CHROMIUM(III) COMPLEXES

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Title TRANSITION-METAL SACCHARIDE CHEMISTRY AND BIOLOGY - SYNTHESIS, CHARACTERIZATION, REDOX BEHAVIOR, BIOINTERACTION AND DATA CORRELATIONS OF DINUCLEAR CHROMIUM(III) COMPLEXES
 
Creator KAIWAR, SP
RAGHAVAN, MSS
RAO, CP
 
Subject sugar-type ligands
d-fructose
d-glucose
iron(iii) complexes
potassium chromate
amino-acid
ions
coordination
derivatives
oxidation
 
Description A series of dinuclear chromium(III) complexes has been synthesised by reduction of chromate by a variety of saccharides and related compounds. The complexes have been characterised by various analytical (elemental and ICP-AES analysis, TLC, HPLC) and spectroscopic (UV/VIS, FTIR, EPR, H-1 and C-13 NMR) methods. Antiferromagnetic interactions between the two Cr-III centres have been established by magnetic susceptibility measurements and the hydrolytic stability and redox behaviour of the complexes have been established by extensive electrochemical studies which gave several correlations. The interaction of some of the complexes with DNA has been studied by gel electrophoresis.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-28T23:40:44Z
2011-12-26T12:58:15Z
2011-12-27T05:47:51Z
2011-08-28T23:40:44Z
2011-12-26T12:58:15Z
2011-12-27T05:47:51Z
1995
 
Type Article
 
Identifier JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (10), 1569-1576
0300-9246
http://dx.doi.org/10.1039/dt9950001569
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11870
http://hdl.handle.net/10054/11870
 
Language en