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Woodward-Prevost reaction on diosgenin and its hydroxy analogue: Characterisation and possible mechanism for the formation of unusual products

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Title Woodward-Prevost reaction on diosgenin and its hydroxy analogue: Characterisation and possible mechanism for the formation of unusual products
 
Creator KATOCH, R
BAIG, MHA
TRIVEDI, GK
 
Subject starfish protoreaster-nodosus
marine natural-products
soft coral
polyhydroxylated sterols
sponge
25-monoacetate
6-acetate
saponins
sulfates
 
Description Woodward-Prevost reaction on diosgenin and its 4 beta-hydroxy derivative yielded polyhydroxy steroids, 6-8 and rearranged diosphenol 9 and aldehyde 10; a plausible mechanism involved in their formation is described.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2011-08-29T00:07:25Z
2011-12-26T12:58:15Z
2011-12-27T05:47:53Z
2011-08-29T00:07:25Z
2011-12-26T12:58:15Z
2011-12-27T05:47:53Z
1998
 
Type Article
 
Identifier JOURNAL OF CHEMICAL RESEARCH-S, (9), 524-525
0308-2342
http://dx.doi.org/10.1039/a804016h
http://dspace.library.iitb.ac.in/xmlui/handle/10054/11875
http://hdl.handle.net/10054/11875
 
Language en