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MIXED CHALCOGEN CARBONYL-COMPOUNDS .4. REACTIVITY OF FE2(CO)6(MU-STE) AND FE3(CO)9(MU-3-S)(MU-3-TE) TOWARDS COORDINATIVELY UNSATURATED SPECIES

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Title MIXED CHALCOGEN CARBONYL-COMPOUNDS .4. REACTIVITY OF FE2(CO)6(MU-STE) AND FE3(CO)9(MU-3-S)(MU-3-TE) TOWARDS COORDINATIVELY UNSATURATED SPECIES
 
Creator MATHUR, P
CHAKRABARTY, D
HOSSAIN, MM
RASHID, RS
 
Subject cluster synthesis
fe2ru2(co)11(mu-4-te)2
fe2ru(co)9(mu-3-te)2
fe3(mu-3-te)2(co)9
complexes
 
Description Using Fe2(CO)6(mu-STe) and Fe3(CO)9(mu-3-S)(mu-3-Te) for the addition of coordinatively unsaturated species, the following new mixed metal, mixed chalcogen compounds have been obtained: Fe2(CO)6(mu-3-S)(mu-3-Te)M(PPh3)2 (M = Pt, Pd), Fe2Ru(CO)9(mu-3-S)(mu-3-Te) and Fe4-xRux(CO)11(mu-4-S)(mu-4-Te) (x = 0-2). The formation of the triphenylphosphine derivatives, Fe3(CO)9-x(PPh3)x(mu-3-S)(mu-3-Te) (x = 1, 2) and Fe3(CO)9(PPh3)(mu-3-S)(mu-3-Te) are also reported.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T10:10:13Z
2011-12-26T12:48:37Z
2011-12-27T05:48:13Z
2011-07-29T10:10:13Z
2011-12-26T12:48:37Z
2011-12-27T05:48:13Z
1991
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 420(1), 79-86
0022-328X
http://dx.doi.org/10.1016/0022-328X(91)86447-X
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7672
http://hdl.handle.net/10054/7672
 
Language en