Record Details


Field	Value

Title	INTERPRETATION OF ADSORPTION-ISOTHERMS AT ABOVE-CRITICAL TEMPERATURES USING A MODIFIED MICROPORE FILLING MODEL

Creator	SHETHNA, HK BHATIA, SK

Subject	carbons equation

Description	A new micropore filling model, which has a Henry's law region and predicts an upper limit to micropore size, is applied here to adsorption at supercritical temperatures. Data obtained here on the adsorption of methane and carbon dioxide on activated carbons are interpreted in terms of this model, while utilizing independently obtained pore size distributions. The results show that the contributions of micropore filling and mesopore surface adsorption can vary considerably with temperature as well as adsorbate, because of the dependency of the upper limit of micropore size in which filling occurs on these variables. In light of these findings it appears that concepts such as micropore volume and mesopore surface area are not reliable characteristics of the pore structure as they vary with process conditions.

Publisher	AMER CHEMICAL SOC

Date	2011-07-14T08:47:48Z 2011-12-26T12:48:18Z 2011-12-27T05:48:23Z 2011-07-14T08:47:48Z 2011-12-26T12:48:18Z 2011-12-27T05:48:23Z 1994

Type	Article

Identifier	LANGMUIR, 10(3), 870-876 0743-7463 http://dx.doi.org/10.1021/la00015a043 http://dspace.library.iitb.ac.in/xmlui/handle/10054/3914 http://hdl.handle.net/10054/3914

Language	en

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