Hexaacetato derivative of calix(6)arene for the solvent extraction separation of lead(II)
DSpace at IIT Bombay
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Title |
Hexaacetato derivative of calix(6)arene for the solvent extraction separation of lead(II)
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Creator |
MALKHEDE, DD
PHADKE, M DHADKE, PM KHOPKAR, SM |
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Subject |
eosin
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Description |
Lead(ll) was quantitatively extracted with 1 x 10(.4) M Calix(6)arene hexaacetato derivative in xylene at pH 6.0 with 4 M nitric acid. It was stripped and determined spectrophotometrically at 520 nm using 4-(2-pyridylazo) resorcinol. Although silver, indium and palladium showed strong interference, metals like molybdenum, selenium, chromium, tellurium associated in. minerals or tin, antimony, zinc, bismuth, thallium associated in, low fusible alloys are tolerated in the ratio 1:10. Anions, alkali and alkaline earths are well tolerated. The method was applied for determination of lead in, real samples like a solder. The reproducibility, expressed as Relative Standard Deviation is +/- 1.2%.
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Publisher |
SPECTROSCOPY SOC CANADA, OTTAWA
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Date |
2011-08-29T07:42:38Z
2011-12-26T12:58:29Z 2011-12-27T05:48:32Z 2011-08-29T07:42:38Z 2011-12-26T12:58:29Z 2011-12-27T05:48:32Z 1998 |
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Type |
Article
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Identifier |
CANADIAN JOURNAL OF ANALYTICAL SCIENCES AND SPECTROSCOPY, 43(5), 144-148
1205-6685 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12017 http://hdl.handle.net/10054/12017 |
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Language |
en
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