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Fe(CO)(5) promoted C-S bond activation and formation of an unusual C(2)S(3) ligand in [{Fe(2)(CO)(6)}(2)(mu-C(2)S(3))]

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Title Fe(CO)(5) promoted C-S bond activation and formation of an unusual C(2)S(3) ligand in [{Fe(2)(CO)(6)}(2)(mu-C(2)S(3))]
 
Creator MATHUR, P
BOODIDA, S
JI, RS
MOBIN, SM
 
Subject crystal-structures
carbon-disulfide
structural-characterization
complexes
cleavage
cs2
cluster
fe2(co)6(mu-se2)
elimination
derivatives
iron pentacarbonyl
carbon disulfide
c-s bond cleavage
crystal structure
 
Description Photolysis of a hexane solution containing Fe(CO)(5) and CS(2) leads to desulfurization and formation of a novel cluster [{Fe(2)(CO)(6)}(2)(mu-C(2)S(3))] (1). Its molecular structure was determined by single crystal X-ray diffraction methods and shown to consist of two distinct Fe(2)(CO)(6) units linked by an unusual C(2)S(3) unit. (C) 2009
 
Publisher ELSEVIER SCIENCE SA
 
Date 2011-07-27T22:29:04Z
2011-12-26T12:58:35Z
2011-12-27T05:48:47Z
2011-07-27T22:29:04Z
2011-12-26T12:58:35Z
2011-12-27T05:48:47Z
2009
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694(18), 3043-3045
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2009.05.023
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7342
http://hdl.handle.net/10054/7342
 
Language en