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PHOTOCHEMICAL REACTIVITIES OF PHENYL SELENO AND TELLURO ESTERS

DSpace at IIT Bombay

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Field Value
 
Title PHOTOCHEMICAL REACTIVITIES OF PHENYL SELENO AND TELLURO ESTERS
 
Creator SINGH, AK
ROY, M
 
Description Direct excitation (300 nm) of phenyl seleno and phenyl telluro benzoate in n-hexane, methanol, and silica gel matrices results in the formation of products because of dimerization of PhSe*/PhTe* radicals, and 1,3-migration of the PhTe* radical. Reactivity of the photogenerated radicals formed as a result of cleavage of the -CO-X-bond is markedly influenced by the diffusion characteristics of the radicals and the nature of group X.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T11:12:02Z
2011-12-26T12:48:39Z
2011-12-27T05:49:27Z
2011-07-29T11:12:02Z
2011-12-26T12:48:39Z
2011-12-27T05:49:27Z
1992
 
Type Article
 
Identifier JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 69(1), 49-52
1010-6030
http://dx.doi.org/10.1016/1010-6030(92)85259-W
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7690
http://hdl.handle.net/10054/7690
 
Language en