Record Details

Hydrogenation of alpha-acetamidocinnamic acid with polystyrene-supported rhodium catalysts

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Hydrogenation of alpha-acetamidocinnamic acid with polystyrene-supported rhodium catalysts
 
Creator BHADURI, S
LAHIRI, GK
MUNSHI, P
 
Subject enantioselective hydrogenation
complexes
carbonyls
rh6(co)16
alumina
silica
catalyst
rhodium
polystyrene supported
 
Description Divinylbenzene cross-linked chloromethylated polystyrene has been functionalised with cinchonine, ephedrine, 3S,4S-N-benzylpyrrolidinediol and four achiral amines. The resins have been used as supports for anchoring [Rh(CO)(2)Cl-2](-). The polymer-supported complex has been tested as a catalyst precursor for the hydrogenation of alpha-acetamidocinnamic acid. Highest rate and modest enantioselectivity are obtained with cinchonine functionalized polymer-supported complex. This complex also undergoes reversible decarbonylation. (C) 2000 Elsevier Science S.A. .
 
Publisher ELSEVIER SCIENCE SA
 
Date 2011-07-28T09:20:50Z
2011-12-26T12:58:50Z
2011-12-27T05:49:28Z
2011-07-28T09:20:50Z
2011-12-26T12:58:50Z
2011-12-27T05:49:28Z
2000
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 606(2), 151-155
0022-328X
http://dx.doi.org/10.1016/S0022-328X(00)00334-X
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7362
http://hdl.handle.net/10054/7362
 
Language en