Y-89 NMR probe of Zn induced local magnetism in YBa2(Cu1-yZny)(3)O6+x
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Title |
Y-89 NMR probe of Zn induced local magnetism in YBa2(Cu1-yZny)(3)O6+x
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Creator |
MAHAJAN, AV
ALLOUL, H COLLIN, G MARUCCO, JF |
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Subject |
c cuprate la1.85sr0.15cuo4
spin-glass rb2cu1-xcoxf4 aligned yba2cu3o7 powder neutron-scattering o-17 nmr doped yba2cu3o7 pair-breaking normal-state al impurity substitution |
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Description |
We present detailed data and analysis of the effects of Zn substitution on the planar Cu site in YBa2Cu3O6+x (YBCO6+x) as evidenced from our Y-89 NMR measurements on oriented powders. For x much less than 1 we find additional NMR lines which are associated with the Zn substitution. From our data on the intensities and temperature dependence of the shift, width, and spin-lattice relaxation rate of these resonances, we conclude that the spinless Zn 3d(10) state induces local moments on the near-neighbour (nn) Cu atoms. Additionally, we conjecture that the local moments actually extend to the farther Cu atoms with the magnetization alternating in sign at subsequent nn sites. We show that this analysis is compatible with ESR data taken on dilute Gd doped (on the Y site) and on neutron scattering data reported recently on Zn substituted YBCO6+x. For optimally doped compounds Y-89 nn resonances are not detected, but a large T-dependent contribution to the Y-89 NMR linewidth is evidenced and is also attributed to the occurence of a weak induced local moment near the Zn. These results are compatible with macroscopic magnetic measurements per formed on YBCO6+x samples prepared specifically in order to minimize the content of impurity phases. We find significant differences between the present results on the underdoped YBCO6+x samples and Al-27 NMR data taken on Al3+ substituted on the Cu site in optimally doped La2CuO4. Further experimental work is needed to clarify the detailed evolution of the impurity induced magnetism with hole content in the cuprates.
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Publisher |
SPRINGER VERLAG
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Date |
2011-08-30T10:36:39Z
2011-12-26T12:58:54Z 2011-12-27T05:49:35Z 2011-08-30T10:36:39Z 2011-12-26T12:58:54Z 2011-12-27T05:49:35Z 2000 |
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Type |
Article
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Identifier |
EUROPEAN PHYSICAL JOURNAL B, 13(3), 457-475
1434-6028 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12285 http://hdl.handle.net/10054/12285 |
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Language |
en
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