Kinetically balanced Gaussian basis-set approach to relativistic Compton profiles of atoms
DSpace at IIT Bombay
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Title |
Kinetically balanced Gaussian basis-set approach to relativistic Compton profiles of atoms
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Creator |
JAISWAL, P
SHUKLA, A |
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Subject |
dirac-fock calculations
x-rays configuration-interaction bound electrons cross-section shell atoms scattering approximation states n2 |
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Description |
Atomic Compton profiles (CPs) are a very important property which provide us information about the momentum distribution of atomic electrons. Therefore, for CPs of heavy atoms, relativistic effects are expected to be important, warranting a relativistic treatment of the problem. In this paper, we present an efficient approach aimed at ab initio calculations of atomic CPs within a Dirac-Hartree-Fock (DHF) formalism, employing kinetically balanced Gaussian basis functions. The approach is used to compute the CPs of noble gases ranging from He to Rn, and the results have been compared to the experimental and other theoretical data, wherever possible. The influence of the quality of the basis set on the calculated CPs has also been systematically investigated.
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Publisher |
AMERICAN PHYSICAL SOC
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Date |
2011-07-17T15:28:13Z
2011-12-26T12:50:22Z 2011-12-27T05:49:40Z 2011-07-17T15:28:13Z 2011-12-26T12:50:22Z 2011-12-27T05:49:40Z 2007 |
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Type |
Article
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Identifier |
PHYSICAL REVIEW A, 75(2), -
1050-2947 http://dx.doi.org/10.1103/PhysRevA.75.022504 http://dspace.library.iitb.ac.in/xmlui/handle/10054/4770 http://hdl.handle.net/10054/4770 |
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Language |
en
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