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Propargyl alcohol derivatives of Fe-2(CO)(6)(mu-EE')(E,E'=S,Se or Te): Synthesis and spectroscopic characterization of (CO)(6)Fe-2{mu-EC(H)=C(CH2OH)E'}(E=Se or Te; E'=S, Se or Te); Crystal structure of (CO)(5)(PPh(3))Fe-2{mu-SeC(CH2OH)=C(H)Se}
DSpace at IIT Bombay
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| Title |
Propargyl alcohol derivatives of Fe-2(CO)(6)(mu-EE')(E,E'=S,Se or Te): Synthesis and spectroscopic characterization of (CO)(6)Fe-2{mu-EC(H)=C(CH2OH)E'}(E=Se or Te; E'=S, Se or Te); Crystal structure of (CO)(5)(PPh(3))Fe-2{mu-SeC(CH2OH)=C(H)Se}
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| Creator |
MATHUR, P
HOSSAIN, MM UMBARKAR, S SATYANARAYANA, CVV PURANIK, VG |
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| Subject |
(propargyl)dicobalt hexacarbonyl cations
chalcogen carbonyl-compounds stabilized carbenium ions complexes iron selenium sulfur tellurium carbonyl propargyl alcohol |
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| Description |
The propargyl alcohol derivatives (CO)(6)Fe-2{mu-EC(H)=C(CH2OH)E'} (E = Se or Te; E' = S, Se or Te) were obtained from the room-temperature reaction of Fe-2(CO)(6)(mu-EE') with propargyl alcohol and were characterized by IR and H-1, C-13, Se-77 and Te-125 NMR spectroscopy. The structure of the PPh(3)-substituted derivative (CO)(5)(PPh(3))Fe-2{mu-SeC(CH2OH)=C(H)Se} was established by a single crystal X-ray diffraction study.
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| Publisher |
ELSEVIER SCIENCE SA LAUSANNE
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| Date |
2011-07-29T12:11:02Z
2011-12-26T12:48:41Z 2011-12-27T05:49:54Z 2011-07-29T12:11:02Z 2011-12-26T12:48:41Z 2011-12-27T05:49:54Z 1996 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 506(1-2), 313-319
0022-328X http://dx.doi.org/10.1016/0022-328X(95)05750-J http://dspace.library.iitb.ac.in/xmlui/handle/10054/7703 http://hdl.handle.net/10054/7703 |
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| Language |
en
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