Cycloaddition of cyclohexa-2,4-dienones with nitroolefins: An unusual regioselectivity and expeditious entry into nitro-bicyclo[2.2.2]octenones
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Title |
Cycloaddition of cyclohexa-2,4-dienones with nitroolefins: An unusual regioselectivity and expeditious entry into nitro-bicyclo[2.2.2]octenones
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Creator |
SINGH, V
SINGH, RB TOSH, DK MOBIN, SM |
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Subject |
diels-alder reactions
masked o-benzoquinones organic-synthesis route cycloaddition diels-alder reaction nitroalkene |
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Description |
Cycloaddition of electron-deficient cyclohexa-2,4-dienones with nitroolefins leading to functionalized bicyclo[2.2.2]octenones with nitro groups is reported. A highly unusual regioselectivity was observed. Crystal structure of one of adducts has also been reported.
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Publisher |
TAYLOR & FRANCIS INC
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Date |
2011-08-30T16:54:36Z
2011-12-26T12:59:04Z 2011-12-27T05:49:56Z 2011-08-30T16:54:36Z 2011-12-26T12:59:04Z 2011-12-27T05:49:56Z 2008 |
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Type |
Article
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Identifier |
SYNTHETIC COMMUNICATIONS, 38(18), 3112-3120
0039-7911 http://dx.doi.org/10.1080/00397910802054263 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12398 http://hdl.handle.net/10054/12398 |
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Language |
en
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