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Studies on the intermolecular cycloaddition of diphenylacetonitrile oxide with substituted olefins

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Title Studies on the intermolecular cycloaddition of diphenylacetonitrile oxide with substituted olefins
 
Creator WANKHEDE, KS
VAIDYA, VV
SURIYANARAYANAN, H
SALUNKHE, MM
TRIVEDI, GK
 
Subject nitrile oxides
1,3-dipolar cycloaddition
derivatives
beta-hydroxy ketones
1,3-dipolar cycloaddition
diphenylacetonitrile oxide
isoxazolines
regioselectivity
 
Description We present our findings on the regio- and stereo chemical outcome of the cycloadditions of sterically crowded diphenylacetonitrile oxide towards mono and disubstituted electron deficient and electron rich olefins. The resultant Delta(2)-isoxazolines are further transformed to their corresponding beta-hydroxy carbonyl compounds employing Curran's protocol.
 
Publisher TAYLOR & FRANCIS INC
 
Date 2011-08-30T18:49:49Z
2011-12-26T12:59:07Z
2011-12-27T05:50:04Z
2011-08-30T18:49:49Z
2011-12-26T12:59:07Z
2011-12-27T05:50:04Z
2008
 
Type Article
 
Identifier SYNTHETIC COMMUNICATIONS, 38(14), 2404-2412
0039-7911
http://dx.doi.org/10.1080/00397910802138777
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12427
http://hdl.handle.net/10054/12427
 
Language en