Record Details

Oxo incorporated metal acetylide complexes

DSpace at IIT Bombay

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Field Value
 
Title Oxo incorporated metal acetylide complexes
 
Creator MATHUR, P
CHATTERJEE, S
 
Subject main-group elements
o bond scission
structural characterization
crystal-structure
catalytic-oxidation
cluster compounds
multiple bonds
transition-metals
acyl ligand
oxygen atom
acetylide
oxo
organometallic
metal
 
Description Studies on organometallic oxo complexes have intensified in recent years due to their implications in catalytic oxidations or as reagents in the oxidation of organic molecules. Synthesis of such complexes containing a hydrocarbon ligand besides the carbonyl and oxo provides an opportunity to obtain complexes with both low oxidation state metal carbonyl fragment and high oxidation state metal oxide fragment in the same molecule. Our attention has been focused on oxo incorporated metal acetylide complexes, in particular, to understand how oxo ligands bond to the metal atoms. Synthetic strategy, structural behavior and reactivity of oxo acetylide metal complexes and clusters are reviewed.
 
Publisher TAYLOR & FRANCIS LTD
 
Date 2011-08-31T03:21:43Z
2011-12-26T12:59:19Z
2011-12-27T05:50:34Z
2011-08-31T03:21:43Z
2011-12-26T12:59:19Z
2011-12-27T05:50:34Z
2005
 
Type Article
 
Identifier COMMENTS ON INORGANIC CHEMISTRY, 26(5-6), 255-286
0260-3594
http://dx.doi.org/10.1080/02603590500403933
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12564
http://hdl.handle.net/10054/12564
 
Language en