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Alpha-hydroxymethylation of conjugated nitroalkenes via the Morita-Baylis-Hillman reaction

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Field Value
 
Title Alpha-hydroxymethylation of conjugated nitroalkenes via the Morita-Baylis-Hillman reaction
 
Creator RASTOGI, NAMRATA
NAMBOOTHIRI, IRISHI NN
COJOCARU, MIRIAM
 
Subject temperature
nitroalkenes
alpha-hydroxymethylation
imidazole
 
Description The Morita–Baylis–Hillman reaction (MBHR) of conjugated nitroalkenes has been successfully carried out for the first time. A variety of aromatic and heteroaromatic nitroalkenes react with formaldehyde at room temperature in the presence of stoichiometric amounts of imidazole and catalytic amounts of anthranilic acid in THF providing moderate to good yields of the multifunctional adducts in most of the cases.
 
Publisher Elsevier
 
Date 2007-12-20T08:49:44Z
2011-11-25T12:19:41Z
2011-12-26T13:05:06Z
2011-12-27T05:51:03Z
2007-12-20T08:49:44Z
2011-11-25T12:19:41Z
2011-12-26T13:05:06Z
2011-12-27T05:51:03Z
2004
 
Type Article
 
Identifier Tetrahedron Letters 45(24), 4745-4748
004-4039
http://dx.doi.org/10.1016/j.tetlet.2004.04.069
http://hdl.handle.net/10054/58
http://dspace.library.iitb.ac.in/xmlui/handle/10054/58
 
Language en