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Mercury chalcogenolates of a ligand having both sterically more bulkier and intramolecularly coordinating features: first isolation of a novel air stable mercury tellurolate

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Title Mercury chalcogenolates of a ligand having both sterically more bulkier and intramolecularly coordinating features: first isolation of a novel air stable mercury tellurolate
 
Creator KANDASAMY, K
SINGH, HB
WOLMERSHAUSER, G
 
Subject monomeric selenolato complexes
center-dot-n
structural-characterization
molecular-structures
crystal-structures
zinc
cadmium
derivatives
precursors
chemistry
mercury
tellurolate
selenolate
crystal structure
 
Description Synthesis and characterization of stable monomeric mercury selenolate (9) and the novel air stable mercury tellurolate (10) incorporating [2-[1-(3,5 dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole], containing both sterically more demanding and intramolecularly coordinating groups have been described here. These complexes were prepared in good yields by oxidative addition of mercury metal to the corresponding dichalcogenides in methanol. FT-IR, multinuclear (H-1, C-13, Se-77 and Te-125) NMR, thermal analysis and mass spectrometric techniques were used to characterize these complexes. The complex 9 was structurally characterized by single-crystal X-ray diffraction analysis. (C) 2004
 
Publisher ELSEVIER SCIENCE SA
 
Date 2011-07-28T12:33:19Z
2011-12-26T12:59:22Z
2011-12-27T05:51:17Z
2011-07-28T12:33:19Z
2011-12-26T12:59:22Z
2011-12-27T05:51:17Z
2005
 
Type Article
 
Identifier INORGANICA CHIMICA ACTA, 358(1), 207-212
0020-1693
http://dx.doi.org/10.1016/j.ica.2004.08.020
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7401
http://hdl.handle.net/10054/7401
 
Language en