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Synthesis and single crystal X-ray structures of N,N '-bis(diphenylphosphinothioyl)piperzine and bis(diphenylphosphinoselenoyl)piperzine

DSpace at IIT Bombay

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Title Synthesis and single crystal X-ray structures of N,N '-bis(diphenylphosphinothioyl)piperzine and bis(diphenylphosphinoselenoyl)piperzine
 
Creator BALAKRISHNA, MS
GEORGE, PP
MAGUE, JT
 
Subject transition-metal chemistry
coordination chemistry
molecular-structures
complexes
ligands
derivatives
palladium(ii)
phosphines
catalysts
insertion
bis( phosphines)
diselenide
disulfide
piperzine derivative
x-ray structure
 
Description The reaction of N, N'-bis(diphenylphosphino) piperzine with elemental sulfur or selenium in toluene under refluxing conditions afforded Ph2P(S)N(C4H8)NP(S)Ph-2 or Ph2P(Se) N(C4H8)NP(Se)Ph-2 in a quantitative yield. The molecular structures were determined by X-ray studies.
 
Publisher TAYLOR & FRANCIS LTD
 
Date 2011-08-31T06:20:08Z
2011-12-26T12:59:24Z
2011-12-27T05:51:25Z
2011-08-31T06:20:08Z
2011-12-26T12:59:24Z
2011-12-27T05:51:25Z
2006
 
Type Article
 
Identifier PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 181(1), 141-146
1042-6507
http://dx.doi.org/10.1080/104265090969225
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12612
http://hdl.handle.net/10054/12612
 
Language en