Mixed-ligand silver(I) complexes containing bis[2-(diphenylphosphino)phenyl]ether and pyridyl ligands
DSpace at IIT Bombay
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Title |
Mixed-ligand silver(I) complexes containing bis[2-(diphenylphosphino)phenyl]ether and pyridyl ligands
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Creator |
BALAKRISHNA, MS
VENKATESWARAN, R MOBIN, SM |
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Subject |
transition-metal chemistry
cross-coupling reactions bite angle diphosphine ligands ruthenium(ii) complexes molecular-structures ru(ii) complexes palladium hydrogenation crystal mixed-ligand silver complexes dpephos polypyridyl zigzag polymer pi-stacking chelate mode of coordination |
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Description |
The reaction of [Ag(2)(k(2)-P,P'-DPEphos)(2)(mu-OTf)(2)] (1) (DPEphos = bis(2-(diphenylphosphino)phenyl]ether) with 1,10-phenanthroline (phen) and 4,4'-bipyridine in equimolar ratios afford, respectively, the mononuclear complex [Ag(k(2)-P,P'-DPEphos)(phen)][OTf] (2) and the coordination polymer [Ag(k(2)-P,P'-DPEphos)(mu-4,4'-bpy)](n)[OTf](n) (3). In complex 3, the silver atoms are bridged by 4,4'-bipyridine units to form a zigzag metallopolymer. (c) 2008
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Publisher |
ELSEVIER SCIENCE SA
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Date |
2011-07-28T13:14:04Z
2011-12-26T12:59:27Z 2011-12-27T05:51:34Z 2011-07-28T13:14:04Z 2011-12-26T12:59:27Z 2011-12-27T05:51:34Z 2009 |
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Type |
Article
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Identifier |
INORGANICA CHIMICA ACTA, 362(1), 271-276
0020-1693 http://dx.doi.org/10.1016/j.ica.2008.02.037 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7410 http://hdl.handle.net/10054/7410 |
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Language |
en
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