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Synthesis of embellished bicyclo[2.2.2]octenones and a sigmatropic 1,2-acyl shift in an excited state: a novel and stereoselective route to (±)-hirsutic acid C and complicatic acid
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Synthesis of embellished bicyclo[2.2.2]octenones and a sigmatropic 1,2-acyl shift in an excited state: a novel and stereoselective route to (±)-hirsutic acid C and complicatic acid
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| Creator |
SINGH, VISHWAKARMA
TOSH, DILIP K SHAIKH, MOBIN M |
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| Subject |
cycloaddition
hirsutic acid complicatic acid |
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| Description |
Formal syntheses of hirsutic acid C and complicatic acid via cycloaddition of cyclohexa-2,4-dienone with methyl methacrylate and a triplet sensitized 1,2-acyl shift are described. The X-ray crystal structure of one of the key intermediates is also reported.
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| Publisher |
Elsevier
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| Date |
2009-02-21T11:27:57Z
2011-11-25T17:19:28Z 2011-12-26T13:05:59Z 2011-12-27T05:51:50Z 2009-02-21T11:27:57Z 2011-11-25T17:19:28Z 2011-12-26T13:05:59Z 2011-12-27T05:51:50Z 2004 |
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| Type |
Article
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| Identifier |
Tetrahedron Letters 45(8), 1729-1732
0040-4039 http://dx.doi.org/10.1016/j.tetlet.2003.12.095 http://hdl.handle.net/10054/730 http://dspace.library.iitb.ac.in/xmlui/handle/10054/730 |
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| Language |
en
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