2-(Dimethylaminomethyl)phenyl phenyl telluride
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
2-(Dimethylaminomethyl)phenyl phenyl telluride
|
|
Creator |
CHAKRABORTY, T
SINGH, HB BUTCHER, RJ |
|
Subject |
cross-coupling reactions
vinylic tellurides organic tellurides crystal n,n-dimethylbenzylamine chloride radii |
|
Description |
The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te center dot center dot center dot N contact [2.8079 (16) angstrom] involving a secondary bonding interaction between the amino N and Te(II) atoms. The Te-C bond [2.136 (2) angstrom] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) angstrom] due to the hypervalent interaction. The bond angle for the trans N-Te-C atoms [164.92 (6)degrees] deviates significantly from linearity.
|
|
Publisher |
WILEY-BLACKWELL PUBLISHING, INC
|
|
Date |
2011-09-01T11:00:39Z
2011-12-26T12:59:37Z 2011-12-27T05:52:08Z 2011-09-01T11:00:39Z 2011-12-26T12:59:37Z 2011-12-27T05:52:08Z 2009 |
|
Type |
Article
|
|
Identifier |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65(), O2562-+
1600-5368 http://dx.doi.org/10.1107/S1600536809038161 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12759 http://hdl.handle.net/10054/12759 |
|
Language |
en
|
|