Record Details

2-(Dimethylaminomethyl)phenyl phenyl telluride

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title 2-(Dimethylaminomethyl)phenyl phenyl telluride
 
Creator CHAKRABORTY, T
SINGH, HB
BUTCHER, RJ
 
Subject cross-coupling reactions
vinylic tellurides
organic tellurides
crystal
n,n-dimethylbenzylamine
chloride
radii
 
Description The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te center dot center dot center dot N contact [2.8079 (16) angstrom] involving a secondary bonding interaction between the amino N and Te(II) atoms. The Te-C bond [2.136 (2) angstrom] trans to the amino group is slightly elongated compared to the other Te-C bond [2.1242 (18) angstrom] due to the hypervalent interaction. The bond angle for the trans N-Te-C atoms [164.92 (6)degrees] deviates significantly from linearity.
 
Publisher WILEY-BLACKWELL PUBLISHING, INC
 
Date 2011-09-01T11:00:39Z
2011-12-26T12:59:37Z
2011-12-27T05:52:08Z
2011-09-01T11:00:39Z
2011-12-26T12:59:37Z
2011-12-27T05:52:08Z
2009
 
Type Article
 
Identifier ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65(), O2562-+
1600-5368
http://dx.doi.org/10.1107/S1600536809038161
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12759
http://hdl.handle.net/10054/12759
 
Language en