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SYNTHESIS AND CHARACTERIZATION OF SOME FERROCENE-CONTAINING TELLUROETHER LIGANDS - CRYSTAL-STRUCTURE OF 1,1'-BIS(PHENYLTELLURO) FERROCENE

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Title SYNTHESIS AND CHARACTERIZATION OF SOME FERROCENE-CONTAINING TELLUROETHER LIGANDS - CRYSTAL-STRUCTURE OF 1,1'-BIS(PHENYLTELLURO) FERROCENE
 
Creator SINGH, HB
REGINI, A
JASINSKI, JP
PAIGHT, ES
BUTCHER, RJ
 
Subject e = s
molecular-structures
telluride ligand
organic halides
complexes
derivatives
reagents
te
ditelluroether
stereodynamics
ferrocene
telluroether
crystal structure
 
Description A series of five monodentate ferrocene tellurium ligands of the type Fe(C5H5)(C(5)H(4)TeR) and five bidentate 1,1'-disubstituted ferrocene tellurium ligands of the type Fe(C(5)H(4)TeR)(2) (R=Me, (n)Bu, C6H5, p-MeOC(6)H(4), p-EtOC(6)H(4)) has been prepared by the reaction of 1,1'-dilithioferrocene with the appropriate ditellurides R(2)Te(2). The ligands have been characterized by their elemental analyses, H-1 and C-13 NMR spectra, mass spectra and cyclic voltammetry studies. The structure of Fe(C5H4TeC6H5)(2) has been determined by single-crystal X-ray diffraction study.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T14:42:47Z
2011-12-26T12:48:45Z
2011-12-27T05:52:11Z
2011-07-29T14:42:47Z
2011-12-26T12:48:45Z
2011-12-27T05:52:11Z
1994
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 464(1), 87-94
0022-328X
http://dx.doi.org/10.1016/0022-328X(94)87014-4
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7743
http://hdl.handle.net/10054/7743
 
Language en