Four-, five- and six-coordinated Zn-II complexes of OH-containing ligands: Syntheses, structure and reactivity
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Title |
Four-, five- and six-coordinated Zn-II complexes of OH-containing ligands: Syntheses, structure and reactivity
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Creator |
DEY, M
RAO, CP SAARENKETO, P RISSANEN, K KOLEHMAINEN, E |
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Subject |
carbonic-anhydrase
crystal-structures vanadium(v) complexes zinc enzymes model derivatives recognition ion monooxovanadium(v) electrochemistry n,o ligands x-ray diffraction hydrogen bonds metalloenzymes zinc |
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Description |
Four-, five- and six-coordinated complexes of Zn-II with OH-rich molecules possessing an ONO binding core were synthesized, characterized and their structures were established by single-crystal X-ray diffraction, The corresponding metal ion geometries were found to be distorted tetrahedral, square pyramidal and octahedral, respectively. The complexes exhibit interesting lattice structures such as layered and corrugated sheets owing to the presence of a number of weak intermolecular interactions. The five-coordinated, water-bound Zn-II complex was studied because of its putative hydrolysis property towards p-nitrophenyl acetate. (C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
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Publisher |
WILEY-V C H VERLAG GMBH
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Date |
2011-09-01T17:04:31Z
2011-12-26T12:59:44Z 2011-12-27T05:52:28Z 2011-09-01T17:04:31Z 2011-12-26T12:59:44Z 2011-12-27T05:52:28Z 2002 |
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Type |
Article
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Identifier |
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (8), 2207-2215
1434-1948 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12827 http://hdl.handle.net/10054/12827 |
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Language |
en
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