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Four-, five- and six-coordinated Zn-II complexes of OH-containing ligands: Syntheses, structure and reactivity

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Title Four-, five- and six-coordinated Zn-II complexes of OH-containing ligands: Syntheses, structure and reactivity
 
Creator DEY, M
RAO, CP
SAARENKETO, P
RISSANEN, K
KOLEHMAINEN, E
 
Subject carbonic-anhydrase
crystal-structures
vanadium(v) complexes
zinc enzymes
model
derivatives
recognition
ion
monooxovanadium(v)
electrochemistry
n,o ligands
x-ray diffraction
hydrogen bonds
metalloenzymes
zinc
 
Description Four-, five- and six-coordinated complexes of Zn-II with OH-rich molecules possessing an ONO binding core were synthesized, characterized and their structures were established by single-crystal X-ray diffraction, The corresponding metal ion geometries were found to be distorted tetrahedral, square pyramidal and octahedral, respectively. The complexes exhibit interesting lattice structures such as layered and corrugated sheets owing to the presence of a number of weak intermolecular interactions. The five-coordinated, water-bound Zn-II complex was studied because of its putative hydrolysis property towards p-nitrophenyl acetate. (C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2011-09-01T17:04:31Z
2011-12-26T12:59:44Z
2011-12-27T05:52:28Z
2011-09-01T17:04:31Z
2011-12-26T12:59:44Z
2011-12-27T05:52:28Z
2002
 
Type Article
 
Identifier EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (8), 2207-2215
1434-1948
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12827
http://hdl.handle.net/10054/12827
 
Language en