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Synthesis and spectroscopic characterisation of CpCoFe(2)(CO)(5)(mu(3)-Se)(2)(P-P) [P-P equals dppm or dppe]: Crystal structure of CpCoFe(2)(CO)(5)(mu(3)-Se)(2)(dppm)

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Title Synthesis and spectroscopic characterisation of CpCoFe(2)(CO)(5)(mu(3)-Se)(2)(P-P) [P-P equals dppm or dppe]: Crystal structure of CpCoFe(2)(CO)(5)(mu(3)-Se)(2)(dppm)
 
Creator MATHUR, P
SEKAR, P
 
Subject chalcogen carbonyl-compounds
cluster complexes
chemistry
reactivity
trinuclear
ligands
sulfur
se
te
iron
cobalt
selenium
phosphorous
carbonyl
cluster
 
Description The room temperature reactions of CpCoFe(2)(CO)(6)(mu(3)-Se)(2) (1) with bis(diphenylphosphino)methane and 1,2-bis(diphenylphosphino)ethane gave the phosphine derivatives of mixed-metal chalcogen clusters, CpCoFe(2)(CO)(5)(mu(3)-Se)(2)(PP)[PP = dppm (2), dppe (3)], respectively. Compounds 2 and 3 have been characterised by IR, and H-1, C-13, P-31 and Se-77 NMR spectroscopy and their compositions have been confirmed by elemental analysis. The structure of 2 has been elucidated by X-ray crystallography. Compound 2 crystallised in the monoclinic, space group P2(1)/n, with a = 20.705(5), b = 11.603(4), c = 32.528(9) Angstrom, beta = 107.38(2)degrees, V = 7108(4) Angstrom(3), Z = 8, D-c = 1.716 Mg m(-3) and R = 0.053 (Rw = 0.057). The structure consists of an Fe2CoSe2 metal core in which the dppm ligand bridges Co and one of the Fe atoms.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T15:22:08Z
2011-12-26T12:48:46Z
2011-12-27T05:52:34Z
2011-07-29T15:22:08Z
2011-12-26T12:48:46Z
2011-12-27T05:52:34Z
1997
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 527(1-2), 29-34
0022-328X
http://dx.doi.org/10.1016/S0022-328X(96)06629-6
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7749
http://hdl.handle.net/10054/7749
 
Language en